Option A: Specific volume
Option B: Work
Option C: Pressure
Option D: Temperature
Correct Answer: Work ✔
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Option A: Van’t-Hoff equation
Option B: Le-Chatelier’s principle
Option C: Arrhenius equation
Option D: None of these
Correct Answer: Van’t-Hoff equation ✔
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Option A: Endothermic
Option B: Exothermic
Option C: Isothermal
Option D: Adiabatic
Correct Answer: Exothermic ✔
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Gibbs free energy at constant pressure and temperature under equilibrium conditions is__________?
Option A: ∞
Option B: 0
Option C: Maximum
Option D: Minimum
Correct Answer: Minimum ✔
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Option A: -94 kcal
Option B: +94 kcal
Option C: > 94 kcal
Option D: < -94 kcal
Correct Answer: +94 kcal ✔
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Option A: Solubility increases as temperature increases
Option B: Solubility increases as temperature decreases
Option C: Solubility is independent of temperature
Option D: Solubility increases or decreases with temperature depending on the Gibbs free energy change
Correct Answer: Solubility increases as temperature decreases ✔
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Option A: Disorder
Option B: Orderly behaviour
Option C: Temperature changes only
Option D: None of these
Correct Answer: Disorder ✔
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Option A: Volume
Option B: Pressure
Option C: Temperature
Option D: All (A), B. and (C)
Correct Answer: Volume ✔
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Option A: Kinematic viscosity
Option B: Work
Option C: Temperature
Option D: None of these
Correct Answer: None of these ✔
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Option A: Bomb
Option B: Separating
Option C: Bucket
Option D: Throttling
Correct Answer: Bomb ✔
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Option A: Equal to its density
Option B: The reciprocal of its density
Option C: Proportional to pressure
Option D: None of these
Correct Answer: The reciprocal of its density ✔
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Option A: Freezing
Option B: Triple
Option C: Boiling
Option D: Boyle
Correct Answer: Triple ✔
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Option A: Steam engine
Option B: Carnot engine
Option C: Diesel engine
Option D: Otto engine
Correct Answer: Steam engine ✔
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Option A: Low pressure and high temperature
Option B: Low pressure and low temperature
Option C: High pressure and low temperature
Option D: High pressure and high temperature
Correct Answer: Low pressure and low temperature ✔
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Option A: Fusion
Option B: Vaporisation
Option C: Transition
Option D: None of these
Correct Answer: Transition ✔
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Option A: Stirling
Option B: Brayton
Option C: Rankine
Option D: None of these
Correct Answer: Stirling ✔
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Option A: Less than
Option B: More than
Option C: Equal to or higher than
Option D: Less than or equal to
Correct Answer: Less than ✔
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Option A: Hess’s
Option B: Kirchoff’s
Option C: Lavoisier and Laplace
Option D: None of these
Correct Answer: A. Hess’s ✔
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Option A: Adiabatic
Option B: Isometric
Option C: Isentropic
Option D: Isothermal
Correct Answer: Isometric ✔
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Option A: Directly proportional to pressure
Option B: Inversely proportional to pressure
Option C: Unity at all pressures
Option D: None of these
Correct Answer: Unity at all pressures ✔
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Option A: 448
Option B: 224
Option C: 22.4
Option D: Data insufficient; can’t be computed
Correct Answer: 448 ✔
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Option A: F = A + PV
Option B: F = E + A
Option C: F = A – TS
Option D: F = A + TS
Correct Answer: F = A + PV ✔
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Option A: Increase
Option B: Decrease
Option C: Not alter
Option D: None of these
Correct Answer: Increase ✔
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The ratio of equilibrium constants (Kp2/Kp1) at two different temperatures is given by__________?
Option A: (R/ΔH) (1/T1 – 1/T2)
Option B: (ΔH/R) (1/T1 – 1/T2)
Option C: (ΔH/R) (1/T2 – 1/T1)
Option D: (1/R) (1/T1 – 1/T2)
Correct Answer: B. (ΔH/R) (1/T1 – 1/T2) ✔
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Option A: Use of only one graph for all gases
Option B: Covering of wide range
Option C: Easier plotting
Option D: More accurate plotting
Correct Answer: Use of only one graph for all gases ✔
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Option A: μ° + RT ln f
Option B: μ°+ R ln f
Option C: μ° + T ln f
Option D: μ° + R/T ln f
Correct Answer: μ° + RT ln f ✔
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Option A: V/T = Constant
Option B: V ∝ 1/T
Option C: V ∝ 1/P
Option D: PV/T = Constant
Correct Answer: V/T = Constant ✔
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Option A: Lewis-Randall
Option B: Margules
Option C: Van Laar
Option D: Both B. & C.
Correct Answer: D. Both B. & C. ✔
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Option A: -2 RT ln 0.5
Option B: -RT ln 0.5
Option C: 0.5 RT
Option D: 2 RT
Correct Answer: -RT ln 0.5 ✔
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Option A: Ice at the base contains impurities which lowers its melting point
Option B: Due to the high pressure at the base, its melting point reduces
Option C: The iceberg remains in a warmer condition at the base
Option D: All A, B. and C
Correct Answer: Due to the high pressure at the base, its melting point reduces ✔
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Option A: Vapor pressure
Option B: Partial pressure
Option C: Chemical potential
Option D: None of these
Correct Answer: Partial pressure ✔
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Option A: Volume, mass and number of moles
Option B: Free energy, entropy and enthalpy
Option C: Both A. and B
Option D: None of these
Correct Answer: C. Both A. and B ✔
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Option A: Binary solutions
Option B: Ternary solutions
Option C: Azeotropic mixture only
Option D: None of these
Correct Answer: Binary solutions ✔
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Option A: Molar heat capacity
Option B: Internal energy
Option C: Viscosity
Option D: None of these
Correct Answer: Internal energy ✔
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Option A: An open system of constant composition
Option B: A closed system of constant composition
Option C: An open system with changes in composition
Option D: A closed system with changes in composition
Correct Answer: A closed system with changes in composition ✔
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Option A: Enthalpy
Option B: Internal energy
Option C: Either A. or B
Option D: Neither A. nor B
Correct Answer: Internal energy ✔
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Option A: Low pressure & high temperature
Option B: High pressure & low temperature
Option C: Low pressure & low temperature
Option D: None of these
Correct Answer: Low pressure & high temperature ✔
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Option A: ΔF = ΔH + T [∂(ΔF)/∂T]P
Option B: ΔF = ΔH – TΔT
Option C: d(E – TS) T, V < 0
Option D: dP/dT = ΔHvap/T.ΔVvap
Correct Answer: ΔF = ΔH + T [∂(ΔF)/∂T]P ✔
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Option A: Concentration of the constituents only
Option B: Quantities of the constituents only
Option C: Temperature only
Option D: All A, B. and C
Correct Answer: D. All A, B. and C ✔
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Option A: Isothermal compression
Option B: Isothermal expansion
Option C: Adiabatic expansion
Option D: Adiabatic compression
Correct Answer: Adiabatic compression ✔
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Option A: Supersaturated
Option B: Superheated
Option C: Both A. and B
Option D: Neither A. nor B
Correct Answer: Superheated ✔
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Option A: Heat pump
Option B: Heat engine
Option C: Carnot engine
Option D: None of these
Correct Answer: Heat pump ✔
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Option A: More in vapour phase
Option B: More in liquid phase
Option C: Same in both the phases
Option D: Replaced by chemical potential which is more in vapour phase
Correct Answer: Same in both the phases ✔
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Option A: Increases
Option B: Decreases
Option C: Remain constant
Option D: Increases linearly
Correct Answer: Increases ✔
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Option A: Reversible isothermal
Option B: Irreversible isothermal
Option C: Reversible adiabatic
Option D: None of these
Correct Answer: Reversible adiabatic ✔
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Option A: No heat and mass transfer
Option B: No mass transfer but heat transfer
Option C: Mass and energy transfer
Option D: None of these
Correct Answer: No mass transfer but heat transfer ✔
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Option A: (∂E/∂ni)S, v, nj
Option B: (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
Option C: (∂H/∂ni)S, P, nj
Option D: All (A), B. and (C)
Correct Answer: D. All (A), B. and (C) ✔
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Option A: Chemical potentials of a given component should be equal in all phases
Option B: Chemical potentials of all components should be same in a particular phase
Option C: Sum of the chemical potentials of any given component in all the phases should be the same
Option D: None of these
Correct Answer: Chemical potentials of a given component should be equal in all phases ✔
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Option A: Bucket
Option B: Throttling
Option C: Separating
Option D: A combination of separating & throttling
Correct Answer: A combination of separating & throttling ✔
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Thermal efficiency of a Carnot engine can approach 100%, only when the temperature of the__________?
Option A: Cold reservoir approaches zero
Option B: Hot reservoir approaches infinity
Option C: Either A. or B
Option D: Neither A. nor B
Correct Answer: C. Either A. or B ✔
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Option A: Zero
Option B: Unity
Option C: Infinity
Option D: None of these
Correct Answer: Zero ✔
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Option A: Decrease on addition of Cl2
Option B: Increase on addition of an inert gas at constant pressure
Option C: Decrease on increasing the pressure of the system
Option D: None of these
Correct Answer: None of these ✔
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Option A: Compressibility
Option B: Work done under adiabatic condition
Option C: Work done under isothermal condition
Option D: Co-efficient of thermal expansion
Correct Answer: Work done under isothermal condition ✔
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Option A: Are more or less constant (vary from 0.2 to 0.3)
Option B: Vary as square of the absolute temperature
Option C: Vary as square of the absolute pressure
Option D: None of these
Correct Answer: Are more or less constant (vary from 0.2 to 0.3) ✔
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Option A: Pressure
Option B: Temperature
Option C: Both A. & B
Option D: Neither A. nor B
Correct Answer: C. Both A. & B ✔
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Option A: Zero
Option B: +ve
Option C: -ve
Option D: Dependent on the path
Correct Answer: Zero ✔
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Option A: Increase the partial pressure of I2
Option B: Decrease the partial pressure of HI
Option C: Diminish the degree of dissociation of HI
Option D: None of these
Correct Answer: Diminish the degree of dissociation of HI ✔
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Option A: Amount of energy transferred
Option B: Direction of energy transfer
Option C: Irreversible processes only
Option D: Non-cyclic processes only
Correct Answer: Direction of energy transfer ✔
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Option A: First law
Option B: Zeroth law
Option C: Third law
Option D: Second law
Correct Answer: Zeroth law ✔
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Option A: Becomes zero
Option B: Becomes infinity
Option C: Equals 1 kcal/kmol °K
Option D: Equals 0.24 kcal/kmol °K
Correct Answer: Becomes infinity ✔
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Option A: Not have a sub-atmospheric vapour pressure at the temperature in the refrigerator coils
Option B: Not have unduly high vapour pressure at the condenser temperature
Option C: Both A. and B
Option D: Have low specific heat
Correct Answer: C. Both A. and B ✔
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Option A: dP/dT = ΔH/TΔV
Option B: ln P = – (ΔH/RT) + constant
Option C: ΔF = ΔH + T [∂(ΔF)/∂T]P
Option D: None of these
Correct Answer: B. ln P = – (ΔH/RT) + constant ✔
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Option A: Kelvin’s
Option B: Antoine’s
Option C: Kirchoff’s
Option D: None of these
Correct Answer: Kirchoff’s ✔
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Option A: Isothermal
Option B: Irreversible
Option C: Adiabatic
Option D: Reversible
Correct Answer: Irreversible ✔
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Option A: Pressure
Option B: Temperature
Option C: Volume
Option D: Molar concentration
Correct Answer: Pressure ✔
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Option A: Gibbs-Duhem
Option B: Maxwell’s
Option C: Clapeyron
Option D: None of these
Correct Answer: Clapeyron ✔
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Option A: Is the analog of linear frictionless motion in machines
Option B: Is an idealised visualisation of behaviour of a system
Option C: Yields the maximum amount of work
Option D: Yields an amount of work less than that of a reversible process
Correct Answer: Yields an amount of work less than that of a reversible process ✔
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Option A: < 0
Option B: > 0
Option C: = 0
Option D: None of these
Correct Answer: < 0 ✔
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Option A: Same as Carnot cycle
Option B: Same as reverse Carnot cycle
Option C: Dependent on the refrigerant’s properties
Option D: The least efficient of all refrigeration processes
Correct Answer: Same as reverse Carnot cycle ✔
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Option A: Pressure
Option B: Temperature
Option C: Both A. & B
Option D: Neither A. nor B
Correct Answer: Temperature ✔
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Option A: Does not depend upon temperature
Option B: Is independent of pressure only
Option C: Is independent of volume only
Option D: Is independent of both pressure and volume
Correct Answer: Is independent of both pressure and volume ✔
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Option A: Reversible and isothermal
Option B: Irreversible and constant enthalpy
Option C: Reversible and constant entropy
Option D: Reversible and constant enthalpy
Correct Answer: Irreversible and constant enthalpy ✔
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Option A: Specific heat at constant pressure (Cp)
Option B: Specific heat at constant volume (Cv)
Option C: Joule-Thompson co-efficient
Option D: None of these
Correct Answer: Joule-Thompson co-efficient ✔
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Option A: Water
Option B: Ammonia
Option C: Freon
Option D: Brine
Correct Answer: Water ✔
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Option A: Conduction
Option B: Convection
Option C: Radiation
Option D: Condensation
Correct Answer: Condensation ✔
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Option A: Doubling the absolute temperature as well as pressure of the gas
Option B: Reducing pressure to one fourth at constant temperature
Option C: Reducing temperature to one fourth at constant pressure
Option D: Reducing the temperature to half and doubling the pressure
Correct Answer: Reducing pressure to one fourth at constant temperature ✔
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Option A: Pressure and temperature
Option B: Reduced pressure and reduced temperature
Option C: Critical pressure and critical temperature
Option D: None of these
Correct Answer: Reduced pressure and reduced temperature ✔
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Option A: Δ H = 0 and ΔS = 0
Option B: Δ H ≠ 0 and ΔS = 0
Option C: Δ H ≠ 0 and ΔS ≠ 0
Option D: Δ H = 0 and ΔS ≠ 0
Correct Answer: Δ H ≠ 0 and ΔS = 0 ✔
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Option A: Superheated
Option B: Desuperheated
Option C: Non-condensable
Option D: None of these
Correct Answer: Superheated ✔
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Option A: Momentum
Option B: Mass
Option C: Energy
Option D: None of these
Correct Answer: Energy ✔
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Option A: Heat capacity of a crystalline solid is zero at absolute zero temperature
Option B: Heat transfer from low temperature to high temperature source is not possible without external
Option C: Gases having same reduced properties behaves similarly
Option D: None of these
Correct Answer: Heat capacity of a crystalline solid is zero at absolute zero temperature ✔
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Option A: (∂T/∂V)S = (∂p/∂S)V
Option B: (∂T/∂P)S = (∂V/∂S)P
Option C: (∂P/∂T)V = (∂S/∂V)T
Option D: (∂V/∂T)P = -(∂S/∂P)T
Correct Answer: (∂V/∂T)P = -(∂S/∂P)T ✔
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Option A: Enhanced COP
Option B: Decreased COP
Option C: No change in the value of COP
Option D: Increased or decreased COP; depending upon the type of refrigerant
Correct Answer: Enhanced COP ✔
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Option A: Third law of thermodynamics
Option B: Second law of thermodynamics
Option C: Nernst heat theorem
Option D: Maxwell’s relations
Correct Answer: Third law of thermodynamics ✔
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Option A: (∂P/∂V)S = (∂P/∂V)T
Option B: (∂P/∂V)S = [(∂P/∂V)T]Y
Option C: (∂P/∂V)S = y(∂P/∂V)T
Option D: (∂P/∂V)S = 1/y(∂P/∂V)T
Correct Answer: (∂P/∂V)S = y(∂P/∂V)T ✔
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Option A: -94 kcal
Option B: > -94 kcal
Option C: < – 94 kcal
Option D: Zero
Correct Answer: Zero ✔
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Option A: Violates second law of thermodynamics
Option B: Involves transfer of heat from low temperature to high temperature
Option C: Both A. and B
Option D: Neither A. nor B
Correct Answer: Involves transfer of heat from low temperature to high temperature ✔
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Option A: 1st
Option B: Zeroth
Option C: 3rd
Option D: None of these
Correct Answer: Zeroth ✔
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Option A: Isobaric
Option B: Isothermal
Option C: Adiabatic
Option D: None of these
Correct Answer: Isothermal ✔
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A. Δ S1 is always Δ SR
C. Δ S1 is always > Δ SR
D. Δ S1 is always = Δ SR
Correct Answer: Δ S1 is always > Δ SR ✔
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Option A: Van Laar equation
Option B: Margules equation
Option C: Wilson’s equation
Option D: All A, B. and C
Correct Answer: D. All A, B. and C ✔
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Option A: Adiabatic
Option B: Isothermal
Option C: Isometric
Option D: None of these
Correct Answer: Isothermal ✔
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Option A: +ve
Option B: -ve
Option C: 0
Option D: Either of the above three; depends on the nature of refrigerant
Correct Answer: 0 ✔
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Option A: A = H – TS
Option B: A = E – TS
Option C: A = H + TS
Option D: None of these
Correct Answer: B. A = E – TS ✔
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Option A: Fugacity
Option B: Activity co-efficient
Option C: Free energy
Option D: None of these
Correct Answer: None of these ✔
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Option A: Isothermal
Option B: Adiabatic
Option C: Isentropic
Option D: None of these
Correct Answer: Isothermal ✔
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